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Synthesis of 2-substituted O,O-bis(trimethylsilyl) alkylphosphonites with aryl and heterocyclic fragments and their amino or amido derivatives

✍ Scribed by Andrey A. Prishchenko; Mikhail V. Livantsov; Olga P. Novikova; Ludmila I. Livantsova; Valery S. Petrosyan

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
334 KB
Volume
19
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

Free‐radical addition of bis(trimethyl‐siloxy)phosphine to various functionalized alkenes with aryl and heterocyclic fragments is proposed as a convenient procedure for the synthesis of new 2‐substituted alkylphosphonites of corresponding structures. Also the new functionalized derivatives of these phosphonites, including various amino and amido groups as well as certain properties of these compounds, are presented. © 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:345–351, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20431

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