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Synthesis of functionalized 2-trimethylsiloxy-substituted O-trimethylsilyl alkylphosphonites, their analogues, and derivatives

✍ Scribed by Andrey A. Prishchenko; Mikhail V. Livantsov; Olga P. Novikova; Ludmila I. Livantsova; Valery S. Petrosyan

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
117 KB
Volume
19
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

Nucleophilic addition of trimethylsilyl esters of tricoordinate organophosphorus acids to several functionalized alkylene oxides is proposed as convenient methods for the synthesis of new 2‐trimethylsiloxysubstituted alkylphosphonites, their analogues, and derivatives. Also the new functionalized derivatives of these phosphonites, including amino, carboxy, or sulfo groups as well as certain properties of these compounds, which may be the important precursors of new functionalized 2‐hydroxyalkylorganophosphorus acids, are presented. © 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:450–454, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20453

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