A stereoselective synthesis of the core fragment 4 of terpentecin is presented. The five contiguous asymmetric centers of 4 were prepared from enone 8 via a sequence of steps highlighted by: oxygenation of the C6 center by epoxidation of enone 18, methylenation of the C8 carbonyl group of 20 by mean
โฆ LIBER โฆ
Synthesis of the Fully Functionalized Bicyclic Core of Garsubellin A
โ Scribed by Nicolaou, K. C.; Pfefferkorn, J. A.; Kim, S.; Wei, H. X.
- Book ID
- 127117572
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 49 KB
- Volume
- 121
- Category
- Article
- ISSN
- 0002-7863
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