Studies toward the total synthesis of ga
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Hiroyuki Usuda; Motomu Kanai; Masakatsu Shibasaki
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Article
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2002
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Elsevier Science
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French
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During studies directed toward the total synthesis of garsubellin A, synthesis of 8-deprenyl-garsubellin A, containing three (of four in the natural product) stereocenters with the proper configurations, was achieved. Key steps are a one-pot lactone formation, a formal migration to the bicyclo[3.3.1