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Synthesis of ( R )-3,4-Diaminobutanoic Acid by Desymmetrization of Dimethyl 3-(Benzylamino)glutarate through Enzymatic Ammonolysis

✍ Scribed by López-García, Mónica; Alfonso, Igancio; Gotor, Vicente

Book ID
121694485
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
70 KB
Volume
68
Category
Article
ISSN
0022-3263

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Desymmetrization of dimethyl 3-substitut
Desymmetrization of dimethyl 3-substituted glutarates through enzymatic ammonolysis and aminolysis reactions
✍ Mónica López-Garcı́a; Ignacio Alfonso; Vicente Gotor 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 157 KB

The desymmetrization of differently 3-substituted glutarates through enzymatic aminolysis and ammonolysis has been studied. The effect of the diester and nucleophile structures, the enzymatic preparation as well as the reaction conditions have been compared in terms of both the chemical yield and en