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Synthesis of Proline-Based N-Heterocyclic Carbene Ligands

✍ Scribed by Zhao, Yang; Gilbertson, Scott R.


Book ID
121495065
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
579 KB
Volume
16
Category
Article
ISSN
1523-7060

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## Abstract The reaction of 2‐azidophenyl isocyanide (**7**) with [M(CO)~5~(thf)] (M=Cr, W) yields the isocyanide complexes [M(CO)~5~(**7**)] (M=Cr **8**, M=W **9**). Complexes **8** and **9** react with tertiary phosphines such as triphenylphosphane at the azido function of the isocyanide ligand t