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Polyisobutylene-Anchored N -Heterocyclic Carbene Ligands

✍ Scribed by Hongfa, Chayanant; Su, Haw-Lih; Bazzi, Hassan S.; Bergbreiter, David E.

Book ID
118152825
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
335 KB
Volume
11
Category
Article
ISSN
1523-7060

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## Abstract The reaction of 2‐azidophenyl isocyanide (**7**) with [M(CO)~5~(thf)] (M=Cr, W) yields the isocyanide complexes [M(CO)~5~(**7**)] (M=Cr **8**, M=W **9**). Complexes **8** and **9** react with tertiary phosphines such as triphenylphosphane at the azido function of the isocyanide ligand t