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Syntheses of effectively-shielded N-heterocyclic carbene ligands

✍ Scribed by Ando, Shin; Matsunaga, Hirofumi; Ishizuka, Tadao

Book ID
118252908
Publisher
Elsevier Science
Year
2013
Tongue
French
Weight
381 KB
Volume
69
Category
Article
ISSN
0040-4020

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## Abstract The reaction of 2‐azidophenyl isocyanide (**7**) with [M(CO)~5~(thf)] (M=Cr, W) yields the isocyanide complexes [M(CO)~5~(**7**)] (M=Cr **8**, M=W **9**). Complexes **8** and **9** react with tertiary phosphines such as triphenylphosphane at the azido function of the isocyanide ligand t