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Synthesis and carbene-transfer reactivity of dimeric nickel carbene cations supported by N-heterocyclic carbene ligands

✍ Scribed by Laskowski, Carl A. ;Hillhouse, Gregory L.


Book ID
120399250
Publisher
The Royal Society of Chemistry
Year
2011
Tongue
English
Weight
253 KB
Volume
2
Category
Article
ISSN
2041-6520

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## Abstract The reaction of 2‐azidophenyl isocyanide (**7**) with [M(CO)~5~(thf)] (M=Cr, W) yields the isocyanide complexes [M(CO)~5~(**7**)] (M=Cr **8**, M=W **9**). Complexes **8** and **9** react with tertiary phosphines such as triphenylphosphane at the azido function of the isocyanide ligand t