N-Heterocyclic Carbenes: Synthesis, Structures, and Electronic Ligand Properties†,‡
✍ Scribed by Herrmann, Wolfgang A.; Schütz, Jan; Frey, Guido D.; Herdtweck, Eberhardt
- Book ID
- 115470629
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 297 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0276-7333
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📜 SIMILAR VOLUMES
## Abstract The reaction of 2‐azidophenyl isocyanide (**7**) with [M(CO)~5~(thf)] (M=Cr, W) yields the isocyanide complexes [M(CO)~5~(**7**)] (M=Cr **8**, M=W **9**). Complexes **8** and **9** react with tertiary phosphines such as triphenylphosphane at the azido function of the isocyanide ligand t
## Abstract N‐Heterocyclic carbenes (NHCs) form stable zwitterionicadducts with a range of heteroallenes, ketenes, and allenes. Although the first representatives of this class of inner salts were first investigated as far back as the 1960s, they have enjoyed a sustained interest from the chemical