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Synthesis of optically pure “open-chain” nucleotide derivatives of asymmetrized tris (hydroxymethyl)methane

✍ Scribed by Giuseppe Guanti; Valeria Merlo; Enrica Narisano

Book ID
103399597
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
784 KB
Volume
51
Category
Article
ISSN
0040-4020

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Enzymes as selective reagents in organic
Enzymes as selective reagents in organic synthesis: Enantioselective preparation of “asymmetrized tris (hydroxymethyl)methane”
✍ Giuseppe Guanti; Luca Banfi; Enrica Narisano 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 171 KB

A new C-4 chiral building block, that is a tn> (hydroxymethyl)methane derivative where the three equivalent hydroxymethyl groups have been differentiated [(THYM)\*], was prepared with excellent enautioselection, through PPL catalysed monohydrolysis of prochiral diacetate 3.