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Asymmetrized tris(hydroxymethyl)methane as precursor of iminosugars: application to the synthesis of isofagomine

✍ Scribed by Giuseppe Guanti; Renata Riva

Book ID
104252603
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
223 KB
Volume
44
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Enzymes as selective reagents in organic
Enzymes as selective reagents in organic synthesis: Enantioselective preparation of β€œasymmetrized tris (hydroxymethyl)methane”
✍ Giuseppe Guanti; Luca Banfi; Enrica Narisano πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 171 KB

A new C-4 chiral building block, that is a tn> (hydroxymethyl)methane derivative where the three equivalent hydroxymethyl groups have been differentiated [(THYM)\*], was prepared with excellent enautioselection, through PPL catalysed monohydrolysis of prochiral diacetate 3.