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Synthesis of novel oxazolines and application in cyanosilylation of prochiral ketones

✍ Scribed by Luo Mei; Li Xiao Xuan; Ke Yu Ping; Yin Hao; Hu Ke Liang; Zhang Jia Hai; Jiang Ying

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
34 KB
Volume
18
Category
Article
ISSN
1042-7163

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✦ Synopsis

Table titled "The Cyanosilylation of Ketones Catalyzed by Rare Earth Complex 2c-La [10]" in column 2 of page 681 should be Table 4. The online version of this paper has been corrected.

πŸ“œ SIMILAR VOLUMES

Synthesis of novel oxazolines and applic
Synthesis of novel oxazolines and application in cyanosilylation of prochiral ketones
✍ Luo Mei; Li Xiao Xuan; Ke Yu Ping; Yin Hao; Hu Ke Liang; Zhang Jia Hai; Jiang Yi πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 206 KB

## Abstract A new family of oxazolines was synthesized in high yields and was characterized by NMR, IR, and MS. Oxazoline–lanthanide complexes, as the novel Lewis acid catalysts, were applied to the asymmetric cyanosilylation of ketones that gave the corresponding cyanohydrin trimethylsilyl ethers

Synthesis of novel chiral Schiff bases a
Synthesis of novel chiral Schiff bases and their application in asymmetric transfer hydrogenation of prochiral ketones
✍ Zhongqiang Zhou; Yongjun Bian πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 100 KB

## Abstract Novel chiral Schiff bases were synthesized from (+)‐camphor, and their application to asymmetric transfer hydrogenation of prochiral ketones is described. The asymmetric transfer hydrogenation reaction could afford excellent conversion rates (up to 97.3%) and up to 27.3% enantiomeric ex

Synthesis of N-squaramidoacids and their
Synthesis of N-squaramidoacids and their application in asymmetric borane reduction of prochiral ketones
✍ Ji Zhang; Lei-Lei Li; Hai-Hua Zou; Jun-Jun Chen; Kai-Bei Yu; Ru-Gang Xie πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 427 KB

## Abstract A series of novel __N__‐squaramidoacid ligands were prepared conveniently. Without converting to corresponding amino alcohols, these ligands could be used in asymmetric borane reduction of prochiral aromatic ketones to give secondary alcohols in good to excellent enantiomeric excesses.