## Abstract A new family of oxazolines was synthesized in high yields and was characterized by NMR, IR, and MS. Oxazolineβlanthanide complexes, as the novel Lewis acid catalysts, were applied to the asymmetric cyanosilylation of ketones that gave the corresponding cyanohydrin trimethylsilyl ethers
ChemInform Abstract: Synthesis of Novel Oxazolines and Application in Cyanosilylation of Prochiral Ketones.
β Scribed by Luo Mei; Li Xiao Xuan; Ke Yu Ping; Yin Hao; Hu Ke Liang; Zhang Jia Hai; Jiang Ying
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 28 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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Table titled "The Cyanosilylation of Ketones Catalyzed by Rare Earth Complex 2c-La [10]" in column 2 of page 681 should be Table 4. The online version of this paper has been corrected.
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## Abstract Novel chiral Schiff bases were synthesized from (+)βcamphor, and their application to asymmetric transfer hydrogenation of prochiral ketones is described. The asymmetric transfer hydrogenation reaction could afford excellent conversion rates (up to 97.3%) and up to 27.3% enantiomeric ex