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Synthesis of nitrogen-15 labeled 1,3,5-trinitro-1,3,5-triazacyclohexane (RDX) and 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane (HMX)

✍ Scribed by S. Bulusu; J. Autera; T. Axenrod

Publisher
John Wiley and Sons
Year
1980
Tongue
French
Weight
144 KB
Volume
17
Category
Article
ISSN
0022-2135

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✦ Synopsis

Abstract

Procedures are described for the synthesis of 1,3,5‐trinitro‐1,3,5‐triazacyclohexane (RDX), 1,3,5,7‐tetranitro‐1,3,5,7‐tetraazacyclooctane (HMX) fully labeled with nitrogen‐15.

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H NMR spectra of the energetic materials a -h e x ~y d r o -1 , 3 , 5 -~~o -s -~~e (RDX) and the a-, 8-, yand S-polymorphs of octahydro-1,3,5,7-te~tro-l,3,5,7-tetrazocine (HMX) have been obtained in the solid phase. Primary and secondary dipole-dipole interactions can be observed, which allows calcu