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Synthesis of 14C-labeled octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX)

✍ Scribed by Chi-Yu Huang; Robert A. Mah; Shane S. Que Hee

Publisher: John Wiley and Sons
Year: 1998
Tongue: French
Weight: 293 KB
Volume: 41
Category: Article
ISSN: 0022-2135
DOI: 10.1002/(sici)1099-1344(199805)41:5<377::aid-jlcr85>3.0.co;2-l

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✦ Synopsis

The ({ }^{14} \mathrm{C})-uniformly labeled (UL) explosive, octahydro-1,3,5,7-tetranitro-1,3,5,7tetrazocine (HMX) was synthesized in (40 %) yield by nitrolysis of ({ }^{14} \mathrm{C})-labeled hexamethylenetetramine (hexamine) in the presence of boron trifluoride diethyl etherate as catalyst. The labeled hexamine was syuthesized in (77 %) yield from ({ }^{14} \mathrm{C})-labeled formaldehyde and ammonium hydroxide. The specific activity of ({ }^{14} \mathrm{C})-labeled (\mathrm{HMX}) was (0.24 \mathrm{mCi} / \mathrm{mmol}), a total of (58 \mu \mathrm{C}) was prepared. The radiochemical purity of the labeled substance was (95 %) by HPLC-Liquid scintillation counting and (98 %) by HPLC-UV at (232 \mathrm{~nm})

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