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1H nuclear magnetic resonance of α-hexahydro-1,3,5-trinitro-s-triazine (RDX) and the α-, β-, γ- and δ-polymorphs of octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX)

✍ Scribed by A. G. Landers; T. M. Apple; Cecil Dybowski; T. B. Brill

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
265 KB
Volume
23
Category
Article
ISSN
0749-1581

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✦ Synopsis

H NMR spectra of the energetic materials a -h e x ~y d r o -1 , 3 , 5 -~~o -s -~~e (RDX) and the a-, 8-, yand S-polymorphs of octahydro-1,3,5,7-te~tro-l,3,5,7-tetrazocine (HMX) have been obtained in the solid phase. Primary and secondary dipole-dipole interactions can be observed, which allows calculation of the intramolecular H ---H distances. The spectra suggest that y-HMX, the molecular structure of which is unknown, possesses a chair-chair ring conformation similar to that of a-and S-HMX.

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