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A convenient synthesis of nitrogen-15 and deuterium labelled octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX)

✍ Scribed by M. D. Coburn; D. G. Ott

Publisher
John Wiley and Sons
Year
1981
Tongue
French
Weight
189 KB
Volume
18
Category
Article
ISSN
0022-2135

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✦ Synopsis

Abstract

The preparation of pure octahydro‐1,3,5,7‐tetranitro‐1,3,5,7‐tetrazocine (HMX) labelled with nitrogen‐15 and deuterium was accomplished by sequential nitrolysis of appropriately labelled octahydro‐1,5‐diacetyl‐3,7‐endomethylene‐1,3,5,7‐tetrazocine. The latter compounds were obtained from the reaction of acetic anhydride with hexamethylenetetramine that was specifically labelled by the reaction of the appropriate formaldehyde and ammonia.

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