✦ LIBER ✦

Synthesis of new unsaturated esters, catalysed by Palladium-phosphine complexes

✍ Scribed by G Mignani; F Grass; M Aufrand; D Morel

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 206 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)80405-6

No coin nor oath required. For personal study only.

✦ Synopsis

The palladium-catalysed addition of allylic chlorides to carbonucleophiles leads to the formation of new terpene derivatives. A facile and economical route of phytone is described.

Soluble metal complexes are finding increased use in organic synthesis (1). The palladium (2), molybdenum

(3), iron (4), cobalt (4) and nickel (.5)-catalysed alkylations of a-dicarbonyl and related compounds

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