N-Tosyl allylic sulfoximines undergo rearrangement to allyl sulfinimidic acid esters in the presence of bidentate chiral ligands while N-Cbz allylic sulfoximines give optically active N-Cbz protected T-aminoenones.
Palladium catalysed rearrangement of allylic sulfoximines: Synthesis of γ-amino α,β-unsaturated ketones and esters
✍ Scribed by Dorothy M David; Gareth W O'Meara; Stephen G Pyne
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 208 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-4039
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