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Palladium (0) catalysed rearrangements of allylic sulfoximines to allyl sulfinimidic acid esters and optically active N-Cbz protected γ-amino-enones

✍ Scribed by Stephen G. Pyne; Dorothy M. David; Zemin Dong

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
236 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

N-Tosyl allylic sulfoximines undergo rearrangement to allyl sulfinimidic acid esters in the presence of bidentate chiral ligands while N-Cbz allylic sulfoximines give optically active N-Cbz protected T-aminoenones.

📜 SIMILAR VOLUMES

ChemInform Abstract: Palladium(0)-Cataly
ChemInform Abstract: Palladium(0)-Catalyzed Rearrangements of Allylic Sulfoximines to Allyl Sulfinimidic Acid Esters and Optically Active N-Cbz Protected γ-Amino-enones.
✍ S. G. PYNE; D. M. DAVID; Z. DONG 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

1999 sulfenic acids, sulfinic acids sulfenic acids, sulfinic acids (benzene compounds) Q 0570 ## 05 -096 Palladium(0)-Catalyzed Rearrangements of Allylic Sulfoximines to Allyl Sulfinimidic Acid Esters and Optically Active N-Cbz Protected γ-Amino-enones. -Attempted asymmetric rearrangement of sulf