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A novel synthesis of functionalised tertiary phosphines by palladium catalysed phosphination with triarylphosphines

โœ Scribed by Fuk Yee Kwong; Chi Wai Lai; Yuan Tian; Kin Shing Chan

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
64 KB
Volume
41
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The palladium catalysed Pd-aryl/P-aryl exchange was applied in the synthesis of various functionalised phosphines from their corresponding substituted aryl triflates using triarylphosphines as the phosphinating agents. This method tolerated many functional groups including ketone, aldehyde, ester, nitrile, methyl ether, pyridyl and chloride groups.

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