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Novel phosphine-palladium complex-catalysed regioselective allylation of a Grignard reagent

✍ Scribed by Yuki Takuma; Naoshi Imaki


Publisher
Elsevier Science
Year
1993
Weight
296 KB
Volume
79
Category
Article
ISSN
0304-5102

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ChemInform Abstract: Phosphine-Directed
✍ M. T. DIDIUK; J. P. MORKEN; A. H. HOVEYDA πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 39 KB πŸ‘ 2 views

Phosphine-Directed Stereo-and Regioselective Ni-Catalyzed Reactions of Grignard Reagents with Allylic Ethers. -In the presence of a properly positioned internal Lewis base like a phosphine unit various acyclic and cyclic allylic ethers are regio-and stereoselectively methylated or phenylated. Under