Synthesis of New Cyclic Dialkoxy Disulfides
โ Scribed by Eghbali, Nicolas; Bohle, D. Scott; Harpp, David N.
- Book ID
- 121256843
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 76 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
Dialkoxy disulfides have been used as an alkoxy radical source under photolytic conditions. In addition, this class of disulfide thermally decomposes to deliver S 2 to dienes. We examined benzylic dialkoxy disulfides (X-Ph-CH 2 -O-S-S-O-CH 2 -Ph-X) under thermolytic conditions and observed that the
Allylic dialkoxy disulfides were obtained in good yields and their reactivity has been investigated. Similarly to allylic sulfoxylates, these esters undergo double [2,3]-sigmatropic rearrangement to the appropriate vic-disulfoxides. The latter, being unstable, undergoes spontaneous rearrangement to