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Photolytic, autocatalyzed decomposition of benzylic dialkoxy disulfides

โœ Scribed by DiAndra M. Rudzinski; Ronny Priefer


Book ID
108285389
Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
276 KB
Volume
50
Category
Article
ISSN
0040-4039

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Thermolytic decomposition of benzylic di
โœ DiAndra M. Rudzinski; Mary P. McCourt; Ronny Priefer ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 445 KB

Dialkoxy disulfides have been used as an alkoxy radical source under photolytic conditions. In addition, this class of disulfide thermally decomposes to deliver S 2 to dienes. We examined benzylic dialkoxy disulfides (X-Ph-CH 2 -O-S-S-O-CH 2 -Ph-X) under thermolytic conditions and observed that the