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New Structures from Multiple Rearrangements of Propargylic Dialkoxy Disulfides

โœ Scribed by Braverman, Samuel; Pechenick, Tatiana; Gottlieb, Hugo E.; Sprecher, Milon


Book ID
121256152
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
50 KB
Volume
125
Category
Article
ISSN
0002-7863

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6S,10S)-3,10- Dimethyl-7,11-dimethylidenespiro[5,5]undec-2-en-4-one (1), a new rearranged chamigrane-type sesquiterpenoid with two sp 2 -hybridized carbons in ฮฑ-positions to the spiro-atom, was isolated from the alcoholic extract of the sea hare Aplysia sp. and its structure and absolute configurati