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Generalized Synthesis and Physical Properties of Dialkoxy Disulfides

✍ Scribed by Zysman-Colman, Eli; Harpp, David N.

Book ID
121249902
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
242 KB
Volume
70
Category
Article
ISSN
0022-3263

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Allylic dialkoxy disulfides were obtained in good yields and their reactivity has been investigated. Similarly to allylic sulfoxylates, these esters undergo double [2,3]-sigmatropic rearrangement to the appropriate vic-disulfoxides. The latter, being unstable, undergoes spontaneous rearrangement to