A simple and efficient route to monoprotected E-and Z-2-alkylidene-1 ,Zpropanediols was developed. The key step involves an unusual regio-and stereoselective SR2' Mitsunobu reaction of substituted 3-hydtoxy-2methylenealkenoate. We recently reported that 3.4,~tri-0-benzyl-D-glucose could be used as a
Synthesis of Monoprotected 2-Alkylidene-1,3-propanediols by an Unusual SN2' Mitsunobu Reaction
β Scribed by Charette, Andre B.; Cote, Bernard; Monroc, Sylvie; Prescott, Sylvie
- Book ID
- 120919377
- Publisher
- American Chemical Society
- Year
- 1995
- Tongue
- English
- Weight
- 913 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
A convenient, efficient method for the preparation of benzoxazines is described. 2-(Hydroxyiminomethyl)benzyl alcohols were cyclodehydrated to construct 1H-2,3-benzoxazines by acid-catalyzed intramolecular Mitsunobu reaction. This reaction depended on the geometry of the hydroxyimino moiety in the r
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v