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Synthesis of mixed halogenated trihalomethanes labelled with the stable isotopes 2H or 13C

✍ Scribed by H. L. Vermeulen; R. Sangaiah; L. M. Ball; A. Gold

Publisher
John Wiley and Sons
Year
1995
Tongue
French
Weight
354 KB
Volume
36
Category
Article
ISSN
0022-2135

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✦ Synopsis

Abstract

^2^H and ^13^C‐labelled bromodichloromethane and chlorodibromomethane were obtained in yields of 20 and 12% (for ^2^H) and 6 and 3% (for ^13^C) respectively from a convenient aluminum chloride‐catalyzed reaction of bromoethane with commercially‐available isotopically‐substituted chloroform. The products were purified by preparative gas chromatography and characterized by MS and ^13^C NMR, and by ^1^H for the ^13^C‐labelled material; mass and nuclear magnetic resonance spectroscopy data are reported.

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