Synthesis of macroheterocycles โ Analogs
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A. A. Formanovskii; I. V. Mikhura; S. A. Sokolovskii; A. S. Murakhovskaya; P. B.
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Article
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1988
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Springer US
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English
โ 644 KB
2-(l-Adamantyl)-2-hydroximinoacetonitrile Oxide (IV). A solution of K3Fe(CN) 6 (7.4 g, 22.5 mmole) and KOH (1.26 g, 22.5 mmole) in water (67 ml) was added dropwise with stirring to a solution of glyoxime la (2 g, 9 mmole) in ether (60 ml). The reactionmixture was stirred for 2 h at 25~ the ether lay