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Synthesis of kryptogenin-26-14C and diosgenin-26-14C

✍ Scribed by Raymond D. Bennett; Horst H. Sauer; Erich Heftmann

Publisher
John Wiley and Sons
Year
1969
Tongue
French
Weight
444 KB
Volume
5
Category
Article
ISSN
0022-2135

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✦ Synopsis

Kryptogenin-26-I4C (13) was synthesized from dihydrodiosgenin diacetate (1). The radioactive carbon atom was introduced by the Arndt-Eistert method, and the extra carbon atom was then removed by a carboxy-inversion reaction. Diosgenin-26-I4C (14) was prepared by reduction of kryptogenir~-26-~~C.

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