Synthesis of inosinate trimer I2′p5′I2′pt′I and tetramer I2′p5′I2′p5′I2′p5′I
✍ Scribed by Ramamurthy Charubala; Wolfgang Pfleiderer
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 419 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
SYNTHESIS OF INOSINATE TRIMER
12'p5'12'p5'1 AND TETRAMER 12'pS'I2'pS'I2'pS'I
📜 SIMILAR VOLUMES
The rate of CoLlisional quenching or I(5p' \*P ,,$ by I2 has been determined u&g time-resolved atomic absorption spectroscopy following tunable laser photoiysis of molecular iodine as (3.6 + 0.3) X 10-l' cm3 mole&k-' s-l. Disaepancies between this and earlier results are discussed.
The technique of laser photolysis of alkyl and perfluoroalkyl iodides at 266 nm followed by time-resolved detection of the 1.3-pm emission from I\*('PLI2) has been used to measure the rate constants for deactivation of I\* by CH31, C'HJ, CF31, and CH,. The recommended values are (2.76 2 0.22) x (2.
A bound state \(\mathrm{CO}^{+}\)of \(\mathrm{KI}\) is found, which correlates to the atomic asymptote \(\mathrm{K}\left(4 p^{2} P_{3 / 2}\right)+\) I( \(\left.5 p^{52} P_{3 / 2}\right)\) and has an internuclear distance of \(3.7356(88) \AA\) and a dissociation energy of \(893.1(50)\) \(\mathrm{cm}^