High-Resolution Spectroscopy of Kl Around the Atomic Asymptote K(4p2P3/2) + I(5p5 2P3/2)

✍ Scribed by H. Bluhm; E. Tiemann

• Publisher: Elsevier Science
• Year: 1994
• Tongue: English
• Weight: 307 KB
• Volume: 163
• Category: Article
• ISSN: 0022-2852
• DOI: 10.1006/jmsp.1994.1020

✦ Synopsis

A bound state (\mathrm{CO}^{+})of (\mathrm{KI}) is found, which correlates to the atomic asymptote (\mathrm{K}\left(4 p^{2} P_{3 / 2}\right)+) I( (\left.5 p^{52} P_{3 / 2}\right)) and has an internuclear distance of (3.7356(88) \AA) and a dissociation energy of (893.1(50)) (\mathrm{cm}^{-1}). This is the first clearly characterized excited bound state in (\mathrm{Kl}) and will serve as an intermediate state for multiphoton experiments. ⑲94 Academic Press. Inc.