Recombination of perfluoroalkyl radicals with I(5p5 2P12), I(5p5 2P32) atoms accompanied by radiation
โ Scribed by S.M. Egorov; A.M. Pravilov; V.A. Skorokhodov
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 949 KB
- Volume
- 173
- Category
- Article
- ISSN
- 0301-0104
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๐ SIMILAR VOLUMES
A method is described for the phot~le~c me~~ment of the time-resolved atomic absorption by electronically excited iodine atoms, 1(5'Prn), generated by pulsed irradiation-A kinetic investigation of the decay of these excited atoms yields a vaIlle for the quenching rate constant by mo?ecuku oxygen, th
The rate of CoLlisional quenching or I(5p' \*P ,,$ by I2 has been determined u&g time-resolved atomic absorption spectroscopy following tunable laser photoiysis of molecular iodine as (3.6 + 0.3) X 10-l' cm3 mole&k-' s-l. Disaepancies between this and earlier results are discussed.
A bound state \(\mathrm{CO}^{+}\)of \(\mathrm{KI}\) is found, which correlates to the atomic asymptote \(\mathrm{K}\left(4 p^{2} P_{3 / 2}\right)+\) I( \(\left.5 p^{52} P_{3 / 2}\right)\) and has an internuclear distance of \(3.7356(88) \AA\) and a dissociation energy of \(893.1(50)\) \(\mathrm{cm}^