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Synthesis of “glycospirostanes” via ring-closing metathesis

✍ Scribed by Dorota Czajkowska; Jacek W. Morzycki; Rosa Santillan; Leszek Siergiejczyk


Book ID
116892382
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
682 KB
Volume
74
Category
Article
ISSN
0039-128X

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Racemic and enantiopure targets containing the 6,8-dioxabicycio [3.2.1]octane skeleton, can be conveniently synthesized from monocyclic diene precursors using an intramolecular ruthenium-catalyzed ring-closing metathesis reaction as the key step.