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Synthesis of Catenane Structures via Ring-Closing Metathesis

✍ Scribed by Weck, Marcus; Mohr, Bernhard; Sauvage, Jean-Pierre; Grubbs, Robert H.


Book ID
120443791
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
158 KB
Volume
64
Category
Article
ISSN
0022-3263

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Total synthesis of (βˆ’)- and (Β±)-frontali
✍ Matthias Scholl; Robert H. Grubbs πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 215 KB

Racemic and enantiopure targets containing the 6,8-dioxabicycio [3.2.1]octane skeleton, can be conveniently synthesized from monocyclic diene precursors using an intramolecular ruthenium-catalyzed ring-closing metathesis reaction as the key step.