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Enantioselective Synthesis of (+)-Isolysergol via Ring-Closing Metathesis

✍ Scribed by Deck, Jason A.; Martin, Stephen F.


Book ID
120233336
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
285 KB
Volume
12
Category
Article
ISSN
1523-7060

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Racemic and enantiopure targets containing the 6,8-dioxabicycio [3.2.1]octane skeleton, can be conveniently synthesized from monocyclic diene precursors using an intramolecular ruthenium-catalyzed ring-closing metathesis reaction as the key step.