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Synthesis of fatty acyl derivatives of 24-epibrassinolide

✍ Scribed by Khripach, Vladimir A.; Zhabinskii, Vladimir N.; Tsavlovskii, Dmitrii V.


Book ID
121526378
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
434 KB
Volume
137
Category
Article
ISSN
0960-0760

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Synthesis of tritium labelled 24-epibras
✍ A. Kolbe; V. Marquardt; G. Adam 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 French ⚖ 252 KB

## Abstract Deuterium and tritium 5,7,7‐tris‐labelled 24‐epibrassinolide were prepared by base catalyzed exchange reaction using 24‐epicastasterone tetraacetate 1 or bis‐isopropylidenedioxy‐24‐epicastasterone 8 and labelled water. Baeyer‐Villiger oxidation of the obtained labelled 6‐ketones 2 and 3