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Synthesis of (22R,23R)- and (22S,23S)-[4-14C]-24-EPIBRASSINOLIDE

✍ Scribed by S. Seo; T. Nagasaki; Y. Katsuyama; F. Matsubara; T. Sakata; M. Yoshioka; Y. Makisumi

Book ID
102901122
Publisher
John Wiley and Sons
Year
1989
Tongue
French
Weight
545 KB
Volume
27
Category
Article
ISSN
0022-2135

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✍ Jacek W Morzycki; Izabella JastrzΔ™bska πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 146 KB

## 22S,23S )-23-Bromosapogenins undergo rearrangement to the (22S,23R)-22-hydroxy-23,26-epoxyfurostanes during alkaline hydrolysis. An efficient degradation procedure of sarsapogenin via the corresponding bisfuran to the C 22 lactone is described.