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Synthesis of (22R,23R,24S)-24-Methyl-5α-cholestane-3β,6α,22,23-tetraol, a Biosynthetic Precursor of Brassinolide

✍ Scribed by V. A. Khripach; V. N. Zhabinskii; N. D. Pavlovskii


Book ID
110324313
Publisher
SP MAIK Nauka/Interperiodica
Year
2001
Tongue
English
Weight
53 KB
Volume
37
Category
Article
ISSN
1070-4280

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Stereoselective synthesis of (22R, 23R,
✍ Braja G. Hazra; Padmakar L. Joshi; Bharat B. Bahule; Narshinha P. Argade; Vandan 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 760 KB

## Abstnzck: A new synthesis of the important aldehyde I torn easily available l&Dehydropregnenolone acetate (I6-DPA) in high yield is described. The aidehyde I ip converted to trio1 24, involving a stereaselective generation of all the four chiral centers in the brassinolide side chain. The importa