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Synthesis of enantiomerically pure phosphonic analog of natural aspartic acid

✍ Scribed by O. I. Kolodyazhnyi; O. O. Kolodyazhnaya


Book ID
111460806
Publisher
Springer
Year
2010
Tongue
English
Weight
154 KB
Volume
80
Category
Article
ISSN
1070-3632

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The synthesis of enantiomerically pure,
✍ Stephen Hanessian; Louis-David Cantin; StΓ©phan Roy; Daniele Andreotti; Arthur Go πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 249 KB

The stereocontrolled conjugate addition of anions derived from chiral ot-chlomphosphonamides to ~[~-unsaturated esters leads to the corresponding 3-chlom ester adducts which undergo intramolecular expulsion of the chlorine atom to give the corresponding cyclopmpanes.