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Synthesis of phosphonic analog of glutamic acid

✍ Scribed by Kolodyazhnaya, O. O.; Kolodyazhnaya, A. O.; Kolodyazhnyi, O. I.

Book ID
120443364
Publisher
Springer
Year
2013
Tongue
English
Weight
166 KB
Volume
83
Category
Article
ISSN
1070-3632

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✍ Bernard BessiΓ¨res; AngΓ¨le Schoenfelder; CΓ©line Verrat; AndrΓ© Mann; Paul Ornstein πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 132 KB

A general method based on the sequential reactivities of bis-bromocycloalkenes (3-5) is proposed for the preparation of phosphonocycloalkanes (1a/b-3a/b), representing structural constrained analogues of AP4. For the synthesis of an additional congested AP4 analogue (4), an intramolecular cyclopropa