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Synthesis of doubly labeled enantiomerically pure (R)-mevalonolactone from lactic and malic acid

✍ Scribed by Krohn, Karsten ;Meyer, Annegrete

Book ID: 102901947
Publisher: John Wiley and Sons
Year: 1994
Tongue: English
Weight: 896 KB
Volume: 1994
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.199419940210

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✦ Synopsis

Abstract

Enantiomerically pure ^13^C‐ and ^1^H‐labeled (R)‐mevalonolactones are prepared from (S)‐malic and/or (S)‐lactic acid by Seebachs methodology of self‐reproduction of chirality. The two reaction pathways are complementary in the possibilities of multiple isotopic labeling. The labeling potential is exemplified by the synthesis of a doubly ^13^C, ^1^H‐labeled, one ^13^C‐, and one ^1^H‐labeled mevalonolactone. magnified image

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