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Efficient Synthesis of Enantiomerically Pure α-Ionone from (R)- and (S)-α-Damascone

✍ Scribed by Charles Fehr; Olivier Guntern

Publisher
John Wiley and Sons
Year
1992
Tongue
German
Weight
332 KB
Volume
75
Category
Article
ISSN
0018-019X

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✦ Synopsis

See [14a]. BF,.Et,O-Catalyzed benzyloxylation of 3 led to partially racemized 4 (cu. 70%) [14b]. For other recent bcnzyloxylations of ~,P-unsaturated carbonyl compounds, see [14c].

📜 SIMILAR VOLUMES

ChemInform Abstract: Enzyme-Mediated Syn
ChemInform Abstract: Enzyme-Mediated Synthesis of (R)- and (S)-α-Ionone.
✍ Elisabetta Brenna; Claudio Fuganti; Piero Grasselli; Mara Redaelli; Stefano Serr 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB

Enzyme-Mediated Synthesis of (R)-and (S)-α-Ionone. -Two approaches to the title compounds are presented, which differ only by interchanging the application of traditional techniques of fractional recrystallization and enzyme-mediated reactions. The other two diastereomers of α-ionol are also synthe