Mit der hochstereoselektiven Nitroaldol‐Addition von Nitroacetaldehyd‐diethylacetal 1 und 2‐__O__‐Benzylglycerinaldehyd 2 zu nur zwei der vier möglichen Diastereomere von 3 im Verhältnis 88:12 wurde ein ergiebiger Zugang zu beiden Enantiomeren von 2‐Arabinosamin sowie zu 1,4‐Didesoxy‐1,4‐iminolyxit
Synthesis of D- and L-2-Amino-2-deoxyarabinose and 1,4-Dideoxy-1,4-iminolyxitol by (C2 + C3)-Nitroaldol Addition with 2-O-Benzylglyceraldehyde
✍ Scribed by Dipl.-Chem. Volkmar Wehner; Prof. Dr. Volker Jäger
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- English
- Weight
- 403 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0044-8249
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