From Isolated Polyanions to 1-D Structure: Synthesis and Crystal Structure of Hybrid Fluorides {[(C2H4NH3)3NH]4+}2 · (H3O)+ · [Al7F30]9– and {[(C2H4NH3)3NH]4+}2 · [Al7F29]8– · (H2O)2
✍ Scribed by E. Goreshnik; M. Leblanc; V. Maisonneuve
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- German
- Weight
- 143 KB
- Volume
- 628
- Category
- Article
- ISSN
- 0372-7874
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📜 SIMILAR VOLUMES
In this study are reported the syntheses of three bis(diarylhydrazonecarbonyl 6), and 2-C 4 H 3 S ( 7)], obtained by condensation of corresponding hydrazones with carbon suboxide, C 3 O 2 . The solid-state self-assembly of these carbonyl derivatives, giving rise to polymeric and dimeric networks, is
Treating [Cp\*V(l-Cl) 2 ] 3 (Cp\* = C 5 Me 5 ) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoMe 2 ], respectively, with Me 3 SnF afforded the title compounds [Cp\*V(l-F) 2 ] 4 (1) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoF 2 ] ´THF ( 2). 1 has a tetrameric structure, in which four V atoms can be regarded as being arranged