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New Types of Complexes Based on Re4 Chalcocyanide Clusters − Syntheses and Crystal Structures of [Ni(NH3)5]2[Re4Te4(CN)12]·3.4H2O and [Cd(NH3)5][Cd(NH3)3][Re4Te4(CN)12]·4H2O

✍ Scribed by Yuri V. Mironov; Oliver Oeckler; Arndt Simon; Vladimir E. Fedorov


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
290 KB
Volume
2001
Category
Article
ISSN
1434-1948

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The preparation of complex 1 . ~~4 and its crystal structure analysis have both been reported [S.Xl. The synthesis of the N-methylated nickel chelates roc-5.6 will be reported at a later date. In contrast to ruc-4[8], rw-5,6 are 1101 oxygen-sensitive. ## Cation Inclusion within the Mixed-Valence