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Cation Inclusion within the Mixed-Valence Polyanion Cluster [(MoVIO3)4MoO28(OH)12]8−: Syntheses and Structures of (NH4)7[NaMo16(OH)12O40]·4H2O and (Me2NH2)6[H2Mo16(OH)12O40]

✍ Scribed by Dr. M. Ishaque Khan; Prof. Dr. Achim Müller; Dipl.-Chem. Stephan Dillinger; Dr. Hartmut Bögge; Dr. Qin Chen; Prof. Dr. Jon Zubieta


Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
434 KB
Volume
32
Category
Article
ISSN
0044-8249

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✦ Synopsis


The preparation of complex 1 . ~~4 and its crystal structure analysis have both been reported [S.Xl. The synthesis of the N-methylated nickel chelates roc-5.6 will be reported at a later date. In contrast to ruc-4[8], rw-5,6 are 1101 oxygen-sensitive.

Cation Inclusion within the

Mixed-Valence Polyanion Cluster [(MO~'O,)~MO~,O,,(OH),,~~-: Syntheses and Structures of (NH4),[NaMo,,(OH),,040]-4H,0 and (Me,NH,),[H,Mo,,(OH),,O,ol ** TekpdX: int. code + (315) 443--4070