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Further crystallographic evidence of NH· · ·π (system) and CO· · ·π (system) interactions: The structures of bis(diarylhydrazonecarbonyl)methylene derivatives [{ArPhCNNH—C(O)}2CH2] (Ar = Ph, 2-C5H4N, 2-C4H3S)

✍ Scribed by Paolo Ganis; Giovanni Valle; Luciano Pandolfo; Roberta Bertani; Fabiano Visentin


Publisher
Wiley (John Wiley & Sons)
Year
1999
Tongue
English
Weight
174 KB
Volume
49
Category
Article
ISSN
0006-3525

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✦ Synopsis


In this study are reported the syntheses of three bis(diarylhydrazonecarbonyl 6), and 2-C 4 H 3 S ( 7)], obtained by condensation of corresponding hydrazones with carbon suboxide, C 3 O 2 . The solid-state self-assembly of these carbonyl derivatives, giving rise to polymeric and dimeric networks, is described. In the formation of these structural features, in addition to N-H . . . OAC intermolecular hydrogen bonds, stabilizing intramolecular NH . . . (systems) and intermolecular CO . . .