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Synthesis of D-(-)-[1,7-13C2]shikimic acid

✍ Scribed by Hyeongjin Cho; Lutz Heide; Heinz G. Floss

Publisher
John Wiley and Sons
Year
1992
Tongue
French
Weight
255 KB
Volume
31
Category
Article
ISSN
0022-2135

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✦ Synopsis

Abstract

The chemical synthesis of 99% enriched D(‐)‐[1,7‐^13^C~2~]shikimic acid from [1,2‐^13^C~2~]acetate in 25% overall yield is described. A two‐carbon phosphonate synthon was prepared from [1,2‐^13^C~2~]acetate and used in the shikimate synthesis of Fleet and coworkers.

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